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PKC Inhibitor Peptide

市场价：: 0.00

促销价：: ¥0.00

货号：12-121

品牌：Millipore 密理博

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北京朝阳

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EA (预计3-5工作日到货)

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Replacement Information

重要规格表

CAS号	Hill配方	摩尔质量
150629-67-7	C₃₁H₃₆N₂O₆	532.63 g/mol

价格及供货情况

产品目录编号	库存情况	包装	数量 / 包装	价格	数量
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描述
产品目录编号	852057
Replaces	04-12-1121
品牌系列	Novabiochem®
Alternate Names	N-α-Fmoc-N-ε-1-(4,4-dimethyl-2,6-dioxocyclohex-1-ylidene)ethyl-L-lysine
背景信息	Quasi-orthogonally-protected Lys derivative. The Fmoc group can be removed selectively by treatment with piperidine; the Dde group is cleaved with 2% hydrazine in DMF [1]. When removing Dde in the presence of allyl based protecting groups, allyl alcohol should be included in the deprotection solution to prevent reduction of the allyl group [2]. Lys(Dde) has been employed in the following applications: synthesis of branched peptides [1] and di-epitopic peptides [3]; preparation of MAP core molecules and lipo-MAPs [4, 5]; construction of cyclic peptides [6], TASP molecules [7], templates for combinatorial chemistry [8] and synthetic proteins [9]; preparation of peptides modified at the lysine side-chain [10-14]. It has been reported that Dde can migrate from the side-chain of Lys to the unprotected side-chain of another Lys residue [15], and from the β-amino group to the α-amino group of Dpr [16]. In the former instance, this problem can be overcome by using Fmoc-Lys(ivDde)-OH (852082) or using DBU/DMF (2:98) for Fmoc group removal [15, 17]. Full orthogonality of Dde with Fmoc has recently been demonstrated when hydroxylamine is used for Dde removal [18]. The product number for this product was previously 04-12-1121. To obtain a certificate of analysis (CoA) of a lot that begins with the letter "A", please select the option in the right hand menu "Request a COA for Lot#s starting with A".

参考

产品信息
CAS号	150629-67-7
Hill配方	C₃₁H₃₆N₂O₆
Molar Mass	532.63 g/mol
HS代码	2924 29 70
结构配方图像

应用
应用	Fmoc-Lys(Dde)-OH Novabiochem®. CAS 150629-67-7, molar mass 532.63 g/mol.

生物信息

理化信息
熔点	80 °C 分解

尺寸

材料信息

毒性学信息

GHS安全信息
储存类别	10 - 13 其它液体及固体
WGK	WGK 2 水危害

安全信息

产品使用声明

储存和货运信息
储存	于 -15°C 到 -25°C储存.

包装信息

运输信息

补充信息

规格
Colour (visual)	white to slight yellow to beige
Appearance of substance (visual)	powder
Identity (IR)	passes test
Enantiomeric purity	≥ 99.5 % (a/a)
Purity (TLC(157B))	≥ 98 %
Purity (TLC(CMA2))	≥ 98 %
Assay (HPLC, area%)	≥ 97.0 % (a/a)
Solubility (1 mmole in 2 ml DMF)	clearly soluble
Assay (acidimetric)	≥ 90.0 %
Water (K. F.)	≤ 1.0 %
For TLC-Systems see our General Catalog

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